Hetero-
MoO3/
MoO2@N-doped
carbon nanobelt
anodes (h-
MoO3/
MoO2@NC) with long lifespan and superior rate capability were proposed by a simple in situ reduction tactic, in which pristine
MoO3 was transformed into heterogeneous
MoO3/
MoO2. The hetero-
MoO3/
MoO2 architecture significantly improves the electronic conductivity and affords abundant
oxygen deficiencies. Meanwhile, the synergistic effect of internal
MoO3/
MoO2 heterostructure and outer N-doped
carbon layer (NC) accomplishes a balance of sustainable
potassium/
sodium storage and ultra-durable structure stability. In
potassium ion batteries, the
anodes steadily maintain a reversible capacity of 283 mAh g-1 after 6000 cycles at 0.5 A g-1 and 153 mAh g-1 after 1000 cycles under 2 A g-1, as well as an impressive rate capability of 131 mAh g-1 at 3 A g-1. In
sodium ion batteries, the
anodes purchase a steady capacity of 152 mAh g-1 even after 10,000 cycles at 2 A g-1, and 190 mAh g-1 after 5000 cycles at 0.5 A g-1. Moreover, the h-
MoO3/
MoO2@NC composite possesses a prominent pseudocapacitive effect and good thermal adaptability (-10 to 50 °C) in both KIBs and SIBs. The results indicate that the h-
MoO3/
MoO2@NC composite would be an auspicious material for
potassium/
sodium storage and other ion batteries.