Probing cavitand-organosilane hybrid bilayers via sum-frequency vibrational spectroscopy.

Abstract

Quinoxaline cavitands (QxCav) are transferred by Langmuir-Schaefer method on self-assembled monolayers (SAMs) of octadecyltrichlorosilane (OTS) and N,N-dimethyl-N-octadecyl-3-aminopropyltrimethoxysilyl chloride (DMOAP) on fused silica substrates. The molecular architectures of both the hydrophobic SAMs templates and the hybrid cavitand-organosilanes bilayers at the solid-air interface are investigated and correlated by sum-frequency vibrational spectroscopy. The results show that QxCav are always in the closed vase configuration and orient with their principal axis normal to the substrates. The role of the alkyl chains density in the SAM templates on the QxCav transfer ratio is pointed out.

• Authors: A Aprile, P Pagliusi, F Ciuchi, M P De Santo, R Pinalli, E Dalcanale
• Journal: Langmuir : the ACS journal of surfaces and colloids (Langmuir) Vol. 30 Issue 43 Pg. 12843-9 (Nov 04 2014) ISSN: 1520-5827 [Electronic] United States
• PMID: 25300925 (Publication Type: Journal Article, Research Support, Non-U.S. Gov't)

Chemical References

• Ethers, Cyclic
• Resorcinols
• Silanes
• cavitand
• octadecyltrichlorosilane
• Silicon Dioxide

Topics

• Ethers, Cyclic (chemistry)
• Hydrophobic and Hydrophilic Interactions
• Models, Molecular
• Molecular Conformation
• Resorcinols (chemistry)
• Silanes (chemistry)
• Silicon Dioxide (chemistry)
• Spectrum Analysis
• Surface Properties
• Vibration