The influence of
methanol and
butanol on
soot formation during the pyrolysis of a
toluene primary reference fuel mixture with a research
octane number (RON) of 91 (TPRF91) was investigated by conducting
shock-tube experiments. The TPRF91 mixture contained 17 mol %
n-heptane, 29 mol % iso-
octane, and 54 mol %
toluene. To assess the contribution of individual fuel compounds on
soot formation during TPRF91 pyrolysis, the pyrolysis of
argon diluted (1)
toluene, (2) iso-
octane, and (3)
n-heptane mixtures were also studied. To enable the interpretation of the TPRF91 +
methanol and TPRF91 +
butanol experiments, the influence of both
alcohols on
soot formation during the thermal decomposition of
toluene and iso-
octane was also investigated in a separate series of measurements. Pyrolysis was monitored behind reflected
shock waves at pressures between 2.1 and 4.2 bar and in the temperature range of 2060-2815 K.
Laser extinction at 633 nm was used to determine the
soot yield as a function of reaction time. For selected experiments, the temporal variation in temperature was also measured via time-resolved two-color CO absorption using two
quantum-cascade lasers at 4.73 and 4.56 μm. It was found that
soot formed during TPRF91 pyrolysis is primarily caused by the thermal decomposition of
toluene. Adding
methanol to TPRF91 results in a slight reduction of
soot formation, whereas admixing
butanol results in shifting
soot formation to higher temperatures, but in that case, no overall
soot reduction was observed during TPRF91 pyrolysis. Measured
soot yields were compared to simulations based on a previous and an updated version of a detailed reaction mechanism from the CRECK modeling group [Nobili, A.; Cuoci, A.; Pejpichestakul, W.; Pelucchi, M.; Cavallotti, C.; Faravelli, T. Combust. Flame 2022; 10.1016/j.combustflame.2022.112073]. Rate-of-production analyses for reactions involving BINS at different experimental conditions were carried out. Although in the case of TPRF91 and
toluene pyrolysis, no quantitative agreement was obtained between the experiment and simulation, the comparison nevertheless shows that the new version of the CRECK mechanism is a significant improvement over the previous one. In the case of
n-heptane decomposition and iso-
octane pyrolysis with and without
alcohols, the updated reaction mechanism shows excellent agreement between simulation and measured
soot yields.