Abstract |
Visible-light-driven CO2 reduction to formate with a system consisting of water-soluble zinc tetraphenylporphyrin tetrasulfonate ( ZnTPPS), formate dehydrogenase from Candida boidinii (CbFDH) and methylviologen (MV) in the presence of triethanolamine (TEOA) as an electron donor in an ionic liquid, 1-ethyl-3-methylimidazolium dimethyl phosphate ([EMlm][Me2PO4])/aqueous media was investigated. The catalytic activity of CbFDH for formate oxidation to CO2 and CO2 reduction to formate did not decrease significantly even in [EMlm][Me2PO4]/aqueous media, compared with that in aqueous media. The visible-light-driven MV reduction by the photosensitization of ZnTPPS in [EMlm][Me2PO4]/aqueous media proceeds more efficiently than in the aqueous media system. In the visible-light-driven CO2 reduction to formate system of ZnTPPS, MV and CbFDH with [EMlm][Me2PO4]/aqueous media, moreover, the formate production concentration after 180 min decreased by only 20% as compared with the system in aqueous media.
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Authors | Francesco Secundo, Yutaka Amao |
Journal | RSC advances
(RSC Adv)
Vol. 10
Issue 69
Pg. 42354-42362
(Nov 17 2020)
ISSN: 2046-2069 [Electronic] England |
PMID | 35516778
(Publication Type: Journal Article)
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Copyright | This journal is © The Royal Society of Chemistry. |