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Organoselenium-catalyzed mild dehydration of aldoximes: an unexpected practical method for organonitrile synthesis.

Abstract
Areneselenenic acids (ArSeOH), readily generated from diaryl diselenides and H2O2 by in situ oxidation, were found to be effective and reusable catalysts for dehydration of aldoximes, leading to a practical and scalable preparation of useful organonitriles under mild conditions.
AuthorsLei Yu, Hongyan Li, Xu Zhang, Jianqing Ye, Jianping Liu, Qing Xu, Mark Lautens
JournalOrganic letters (Org Lett) Vol. 16 Issue 5 Pg. 1346-9 (Mar 07 2014) ISSN: 1523-7052 [Electronic] United States
PMID24564392 (Publication Type: Journal Article, Research Support, Non-U.S. Gov't)
Chemical References
  • Nitriles
  • Organoselenium Compounds
  • Oximes
  • Hydrogen Peroxide
Topics
  • Catalysis
  • Dehydration
  • Hydrogen Peroxide (chemistry)
  • Molecular Structure
  • Nitriles (chemical synthesis, chemistry)
  • Organoselenium Compounds (chemical synthesis, chemistry)
  • Oxidation-Reduction
  • Oximes (chemistry)

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