Carbon nanotube/raspberry hollow Pd nanosphere hybrids for methanol, ethanol, and formic acid electro-oxidation in alkaline media.

Abstract

In this paper, raspberry hollow Pd nanospheres (HPNs)-decorated carbon nanotube (CNT) was developed for electro-oxidation of methanol, ethanol, and formic acid in alkaline media. The electrocatalyst was fabricated simply by attaching HPNs onto the surface of CNT which had been functionalized by polymer wrapping. The as-prepared HPN-CNTs (CHPNs) were characterized by transmission electron microscopy (TEM), scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX), and X-ray photoelectron spectroscopy (XPS). The increasing interest and intensive research on fuel cell inspire us to investigate the electrocatalytic properties of the prepared nanostructures. Besides that, previous reports about alkaline other than acidic media could supply a more active environment guide us to examine the electrocatalytic properties in alkaline electrolyte. It is found that this novel hybrid electrocatalyst exhibits excellent electrocatalytic properties and can be further applied in fuel cells, catalysts, and sensors.

• Authors: Zhelin Liu, Bo Zhao, Cunlan Guo, Yujing Sun, Yan Shi, Haibin Yang, Zhuang Li
• Journal: Journal of colloid and interface science (J Colloid Interface Sci) Vol. 351 Issue 1 Pg. 233-8 (Nov 01 2010) ISSN: 1095-7103 [Electronic] United States
• PMID: 20692672 (Publication Type: Journal Article, Research Support, Non-U.S. Gov't)
• Copyright: Copyright 2010 Elsevier Inc. All rights reserved.

Chemical References

• Alkalies
• Formates
• Nanotubes, Carbon
• formic acid
• Ethanol
• Palladium
• Methanol

Topics

• Alkalies (chemistry)
• Catalysis
• Electrochemistry
• Electrons
• Ethanol (chemistry)
• Formates (chemistry)
• Methanol (chemistry)
• Nanospheres (chemistry)
• Nanotubes, Carbon (chemistry)
• Oxidation-Reduction
• Palladium (chemistry)
• Particle Size
• Porosity
• Surface Properties