khafrefungin

inhibits inositol phosphoceramide synthase in fungi; structure in first source

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1.	Dehydration (Water Stress) 03/01/2007 - "[structure: see text] A convergent total synthesis of khafrefungin was accomplished on the basis of (1) the highly stereoselective TiCl4-mediated vinylogous Mukaiyama aldol reaction using vinylketene silyl N,O-acetal and (2) syn-selective aldol reaction of enal 5a and ethyl ketone 6 followed by anti-dehydration under Mitsunobu conditions."