Microstructure, tribological property and corrosion resistance of orthopedic implant materials CoCrW-3 wt.% Cu fabricated by selective
laser melting (SLM) process were systematically investigated with CoCrW as control. Equaxied γ-phase together with the inside {111} < 112 > type twin and platelet ε-phase was found in both the Cu-bearing and Cu-free
alloys. Compared to the Cu-free
alloy, the introduction of 3 wt.% Cu significantly increased the volume fraction of the ε-phase. In both
alloys, the hardness of ε-phase zone was rather higher (~4 times) than that of γ-phase zone. The wear factor of 3 wt.% Cu-bearing
alloy possessed smaller wear factor, although it had higher friction coefficient compared with Cu-free
alloys. The ε-phase in the CoCr
alloy would account for reducing both abrasive and
fatigue wear. Moreover, the Cu-bearing
alloy presented relatively higher corrosion potential Ecorr and lower corrosion current density Icorr compared to the Cu-free
alloy. Accordingly, 3 wt.% Cu addition plays a key role in enhancing the wear resistance and corrosion resistance of CoCrW
alloys, which indicates that the SLM CoCrW-3Cu
alloy is a promising personalized alternative for traditional biomedical implant materials.