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Novel carbocationic rearrangements of 1-styrylpropargyl alcohols.

Abstract
The dehydration and subsequent cyclization reactions of 1-styrylpropargyl alcohols was examined. In the course of these studies, numerous scaffolds were synthesized, including a furan, a cyclopentenone, an acyclic enone and even a naphthalenone. The diversity of these structural motifs lies in novel cascades of reactions originating from a common carbocationic manifold.
AuthorsChristine Basmadjian, Fan Zhang, Laurent Désaubry
JournalBeilstein journal of organic chemistry (Beilstein J Org Chem) Vol. 11 Pg. 1017-22 ( 2015) ISSN: 1860-5397 [Print] Germany
PMID26199656 (Publication Type: Journal Article)

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