Abstract |
The poisoning of wildlife with fly-bait containing the active ingredient methomyl is an intentional and illegal act in many jurisdictions. A case of 2 animals poisoned by methomyl through consumption of tainted bait at multiple stations is described. Although thermally and ultraviolet-labile, methomyl can be identified by gas chromatography-mass spectrometry and is detected in abundance in bait samples; however, it is not readily observed in tissues, owing to its rapid metabolism and elimination. The application of derivatizing functionalities, such as trimethylsilyl groups, stabilizes the methomyl-oxime metabolite to facilitate its detectability during exposure to the relatively harsh conditions of gas chromatography. This brief communication reports on the analytical detection of methomyl in baits and biological samples from poisoned wildlife. Essential to the case were the added determination of a fly-bait coactive ingredient, (Z)-9-tricosene, and identification of a chemical indicator, caffeine, to confirm both the type of pesticide product involved in the poisoning incident and the vehicle used to perpetrate its delivery.
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Authors | John P Buchweitz, Mark Bokhart, Margaret Johnson, Andreas Lehner |
Journal | Journal of veterinary diagnostic investigation : official publication of the American Association of Veterinary Laboratory Diagnosticians, Inc
(J Vet Diagn Invest)
Vol. 25
Issue 6
Pg. 744-9
(Nov 2013)
ISSN: 1943-4936 [Electronic] United States |
PMID | 24105381
(Publication Type: Journal Article)
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Chemical References |
- Alkenes
- Insecticides
- Methomyl
- muscalure
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Topics |
- Alkenes
(analysis)
- Animals
- Animals, Wild
(metabolism)
- Cats
- Gas Chromatography-Mass Spectrometry
(veterinary)
- Gastrointestinal Contents
(chemistry)
- Insecticides
(analysis, metabolism, poisoning)
- Methomyl
(analysis, metabolism, poisoning)
- Michigan
- Opossums
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