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Catalytic deoxydehydration of glycols with alcohol reductants.

Abstract
Top shelf dehydration: Ammonium perrhenate catalysts combined with benzylic alcohol reductants are used for the efficient deoxydehydration of glycols to olefins. The olefin and aldehyde products can be easily separated and isolated. It is also demonstrated that the catalyst can be recovered and reused because of its low solubility in aromatic solvents.
AuthorsCamille Boucher-Jacobs, Kenneth M Nicholas
JournalChemSusChem (ChemSusChem) Vol. 6 Issue 4 Pg. 597-9 (Apr 2013) ISSN: 1864-564X [Electronic] Germany
PMID23532937 (Publication Type: Journal Article, Research Support, Non-U.S. Gov't, Research Support, U.S. Gov't, Non-P.H.S.)
CopyrightCopyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Chemical References
  • Alkenes
  • Glycols
  • Solvents
  • perrhenate
  • Rhenium
  • Benzyl Alcohol
Topics
  • Alkenes (chemistry)
  • Benzyl Alcohol (chemistry)
  • Catalysis
  • Glycols (chemistry)
  • Oxidation-Reduction
  • Rhenium (chemistry)
  • Solvents (chemistry)

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