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Single and multiphase inclusions in metapelitic garnets of the Rhodope Metamorphic Province, NE Greece.

Abstract
Single and multiphase inclusions in garnet porphyroblasts from the diamond-bearing pelitic gneisses were studied by means of combined Raman Spectroscopy and Electron Scanning Microscopy (SEM/EDX). They are either randomly distributed or with preferred orientation within the garnet host and their dimensions vary from less than 5 up to 60 microm. In the single-phase inclusions quartz, rutile, kyanite and graphite dominate. Biotite, zircon, apatite, monazite and allanite are also common. Two types of multiphase inclusions were recognized, hydrous silicate (Type I) and silicate-carbonate (Type II) ones. The carbon-bearing multiphase inclusions predominantly consist of Mg-siderite+graphite+CO(2)+muscovite+quartz formed by a high density carboniferous fluid rich in Fe, Mg, Si and less Ca, Mn, Al and K trapped in the growing garnet in a prograde stage of metamorphism at high-pressure (HP) conditions. The carbon-free multiphase inclusions predominantly consist of biotite+quartz+rutile+/-kyanite+muscovite formed through decompression-dehydration/melting reactions of pre-existing phengite. Single and multiphase inclusions are characterized by polygonal to negative crystal shape formed by dissolution-reprecipitation mechanism between the garnet host and the inclusions during the long lasting cooling period (>100 Ma) of the Kimi Complex.
AuthorsEvripidis Mposkos, Maria Perraki, Sarra Palikari
JournalSpectrochimica acta. Part A, Molecular and biomolecular spectroscopy (Spectrochim Acta A Mol Biomol Spectrosc) Vol. 73 Issue 3 Pg. 477-83 (Aug 2009) ISSN: 1873-3557 [Electronic] England
PMID19181569 (Publication Type: Journal Article)
Chemical References
  • Aluminum Silicates
  • Apatites
  • Carbonates
  • Ferrous Compounds
  • Minerals
  • Silicates
  • muscovite
  • biotite
  • kyanite
  • Carbon Dioxide
  • Quartz
  • zircon
  • Graphite
  • Zirconium
Topics
  • Aluminum Silicates (analysis)
  • Apatites (analysis)
  • Carbon Dioxide (analysis)
  • Carbonates (analysis)
  • Ferrous Compounds (analysis)
  • Geologic Sediments (chemistry)
  • Graphite (analysis)
  • Greece
  • Microscopy, Electron, Scanning
  • Minerals (analysis)
  • Quartz (analysis)
  • Silicates (analysis)
  • Spectrum Analysis, Raman
  • Zirconium (analysis)

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