FTIR spectra and mechanical strength analysis of some selected rubber derivatives.

Abstract

Rubber materials have wide range of commercial applications such as, infant diapers, famine hygiene products, drug delivery devices and incontinency products such as rubber tubes, tyres, etc. In the present work, studies on mechanical properties of some selected rubber materials viz., natural rubber (NR), styrene butadiene rubber (SBR), nitrile butadiene rubber (NBR) and ethylene propylene diene monomer (EPDM) have been carried out in three states viz., raw, vulcanized and reinforced. To enhance the quality of rubber elastomers, an attempt is made to prepare new elastomers called polyblends. In the present study an attempt is made to blend NR with NBR and with EPDM. We here report, a novel approach for the evaluation of various physico-mechanical properties such as mechanical strength, tensile strength, elongation and hardness. The method is simple, direct and fast and involves infrared spectral measurements for the evaluation of these properties. With the applications of modern infrared spectroscopy, the mechanical strength of these rubber materials have been analyzed by calculating the internal standards among the methyl and methylene group vibrational frequencies obtained from FTIR spectroscopy. Also the tensile strength measurements carried out by universal testing machine. The results pertaining physico-mechanical properties of the rubber derivatives undertaken in the present study obtained by IR-based method are in good agreement with data resulted from the standard methods.

• Authors: S Gunasekaran, R K Natarajan, A Kala
• Journal: Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy (Spectrochim Acta A Mol Biomol Spectrosc) Vol. 68 Issue 2 Pg. 323-30 (Oct 2007) ISSN: 1386-1425 [Print] England
• PMID: 17320472 (Publication Type: Journal Article)

Chemical References

• Butadienes
• Elastomers
• Ethylenes
• Styrenes
• ethylene-propylene-diene-monomer
• styrene-butadiene rubber
• Rubber

Topics

• Butadienes (chemistry)
• Elastomers (chemistry)
• Ethylenes (chemistry)
• Mechanics
• Rubber (chemistry)
• Spectroscopy, Fourier Transform Infrared
• Styrenes (chemistry)
• Tensile Strength