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An improved method for emergent decontamination of ocular and dermal hydrofluoric acid splashes.

Abstract
Accidental hydrofluoric acid (HF) splashes often occur in industrial settings. HF easily penetrates into tissues by initial acid action allowing fluoride ions to penetrate deeply, chelating calcium and magnesium. Resultant hypocalcemia and hypomagnesemia can be fatal. This report describes the utilization of Hexafluorine--a hypertonic, amphoteric, chelating decontamination solution--in workplaces where water decontamination followed by calcium gluconate inunction failed to prevent HF burns and systemic toxicity. Between 1998 and 1999, 16 cases of ocular and dermal HF splashes with either 70% HF or 6% HF/15% nitric acid (HNO3) were decontaminated with Hexafluorine at the worksite. HF burns did not develop and medical treatment other than initial decontamination was not reQuired in 12/16 (75%). In 7/16 (44%) cases, lost work time corresponded to duration of hospital observation (mean < 1 d).
AuthorsKjell Soderberg, Petri Kuusinen, Laurence Mathieu, Alan H Hall
JournalVeterinary and human toxicology (Vet Hum Toxicol) Vol. 46 Issue 4 Pg. 216-8 (Aug 2004) ISSN: 0145-6296 [Print] United States
PMID15303400 (Publication Type: Case Reports, Journal Article)
Chemical References
  • Hydrofluoric Acid
Topics
  • Adult
  • Burns, Chemical (diagnosis, epidemiology, pathology)
  • Decontamination
  • Diagnosis, Differential
  • Emergency Treatment
  • Eye Burns (diagnosis, epidemiology, pathology)
  • Female
  • Humans
  • Hydrofluoric Acid (adverse effects)
  • Industry
  • Male
  • Metallurgy
  • Occupational Diseases (diagnosis, epidemiology, pathology)
  • Sweden (epidemiology)

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