Abstract |
The visible spectra of forty-five synthesized polyaluminium ferric chloride ( PAFC) aqueous solutions with different [ OH]/[Al + Fe] (B) and nAl/nFe(molar ratio) were investigated. The results showed that their absorbances A of shoulder at 460 nm are all linear interrelationship with their B. We made the curve of absorbance A of PAFC with same B vs. nAl/nFe, there was a turning point. All of these points just located at the places of pH value rising higher in pH- nAl/nFe diagrams. For these reason, we thought that these points stand for the dynamic equilibrium of OH- between the polynucleus hydroxyl Fe(III) and Al(III). These points made certain relationship among the absorbance A at 460 nm, basicities and total Fe(III) concentration of PAFC solutions.
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Authors | X Zhang, Y Zhao, H Fan, G Yang, Y Lu, D Huang |
Journal | Guang pu xue yu guang pu fen xi = Guang pu
(Guang Pu Xue Yu Guang Pu Fen Xi)
Vol. 20
Issue 4
Pg. 577-80
(Aug 2000)
ISSN: 1000-0593 [Print] China |
PMID | 12945383
(Publication Type: English Abstract, Journal Article)
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