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A dramatic improvement of epoxide selectivity of [Ti,Al]-beta by ion-exchange with quaternary ammonium salts.

Abstract
Ion-exchange of [Ti,Al]-beta with quaternary ammonium acetates greatly enhances the epoxide selectivity in the oxidation of alkenes with hydrogen peroxide; this is due to the selective poisoning of the acid sites without suppressing the oxidation activity of Ti sites.
AuthorsY Goa, P Wu, T Tatsumi
JournalChemical communications (Cambridge, England) (Chem Commun (Camb)) Issue 18 Pg. 1714-5 (Sep 21 2001) ISSN: 1359-7345 [Print] England
PMID12240279 (Publication Type: Journal Article)

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