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aci-reductone oxidase (CO-forming)

from Klebsiella pneumoniae; involved in conversion of 5'-methylthioadenosine to methionine; converts CH3-S-CH2-CH2-CO-C(OH)=CH-O(-) to carbon monoxide + formate + methylthiopropionic acid; synthesized as two enzymes, E-2 and E-2' which bind nickel or cobalt (E-2) or iron (E-2'); amino acid sequence has been determined; GenBank AF102514
Also Known As:
E2 metalloenzyme; acireductone dioxygenase
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