palladium chloride

10/07/2020 - "In this study, we have synthesized and characterized a palladium(II) complex, [PdCl2(µ-PyTT)2]Cl2·4H2O (PdPyTT), with 2-(2-pyridyl)imine-N-(2-thiazolin-2-yl)thiazolidine (PyTT) as a ligand; besides, its cytotoxicity and pro-apoptotic capacity was tested in human promyelocytic leukemia HL-60 cell line. "

08/01/2009 - "In LTT, the use of Na2[PdCl4] results in more positive reactions in Pd allergy testing which are in concordance with positive reactions to PdCl2 and NiCl2."
10/01/2019 - "Delayed hypersensitivity to palladium dichloride: 15-year retrospective study in a skin allergy unit."
11/01/2013 - "Furthermore, Na2 PdCl4 seems to be a more sensitive test substance than PdCl2 for the detection of palladium allergy."
08/01/2009 - "After determining optimal nontoxic and nonmitogenic concentrations for Na2[PdCl4], blood samples from 105 patients with clinical suspicion of metal allergy were tested with an LTT called memory lymphocyte immuno stimulation assay for Na2[PdCl4], PdCl2 and NiCl2. "
02/05/2023 - "The Pd-induced allergy mouse was generated by two sensitizations with PdCl2, plus a lipopolysaccharide solution into the postauricular skin followed by a single Pd challenge of the buccal mucosa. "

05/01/1992 - "During a 15-month period, 536 patients being investigated for suspected contact dermatitis were patch tested with the European standard series and palladium chloride 1% pet. "
04/01/2018 - "Among allergens of the German Contact Dermatitis Research Group series 'dental metals', positive reactions were less frequent and were mainly to palladium chloride (n = 6). "
01/01/2002 - "There was no statistically significant difference in the total contact sensitization rate between atopics and non-atopics, but contact sensitivity to nickel sulfate and palladium chloride was significantly higher among atopics. "
08/01/1992 - "Contact dermatitis from metallic palladium in patients reacting to palladium chloride."
09/01/2001 - "Men aged 18 to 43 years (n = 118) were patch-tested using the North American Contact Dermatitis Group's protocol to nickel sulfate 2.5%, gold sodium thiosulfate 0.5%, cobalt chloride 1%, and palladium chloride 1%. "

08/02/2013 - "In addition, palladium chloride ligands can mediate proton transfer to promote dehydration when direct intramolecular proton transfer between diol groups is impossible."
11/10/2005 - "Mild and reversible dehydration of primary amides with PdCl2 in aqueous acetonitrile."
01/01/2016 - "A new method for one-pot synthesis of β-substituted and β,β-disubstituted α,β-unsaturated methyl ketones from homoallyl alcohols by sequential PdCl2/CrO3-promoted Wacker process followed by an acid-mediated dehydration reaction has been developed. "

01/01/2023 - "Furthermore, Pdcl2 null spermatozoa have rounded heads, similar to globozoospermia in humans. "
01/01/2023 - "We recently found that male PDCL2 knockout mice are sterile due to globozoospermia caused by impaired sperm head formation, indicating that PDCL2 is a potential target for male contraception. "
10/17/2022 - "Patients with teratozoospermia exhibit low phosducin-like protein (Pdcl2) expression. "